Introduction irradiation assisted stress corrosion cracking iascc is a term which has been used in recent years. Irradiation assisted stress corrosion cracking iascc is an important effect limiting the integrity of light water reactor lwr core components, especially with respect to longterm oper ations. Irradiation assisted stress corrosion cracking iascc. Due to the embrittlement of grain boundaries or other defects that can serve as crack initiators, the addition of radiation attack at cracks can cause intergranular stress corrosion cracking. Such cracks have been seen in a number of internal components in boiling water reactors bwrs. Effects of irradiation on intergranular stress corrosion. The irradiationassisted stress corrosion cracking iascc issue. Since the irradiation damage processes are similar for both. Irradiation assisted stress corrosion cracking iascc refers to the processes by which irradiation enhances the inherent susceptibility of alloys to stress corrosion cracking scc. Irradiationassisted stress corrosion cracking is a key materials degradation issue in todays nuclear power reactor fleet and affects critical structural components within the reactor core. Liquid metal cracking lmc, usually a physicochemical process. The probable role of some or all of these failure mechanisms in core component failures observed to date, and in experiments ostensibly designed to observe iascc, is critically examined. Irradiation assisted, stress corrosion cracking iascc of austenitic stainless steel ss is known to occur in water environments at temperatures near 288c, but very little information exists to indicate susceptibility as temperatures are reduced. Thermally sensitized 304 stainless steels, irradiated up to 1.
This report summarizes work performed at argonne national laboratory on irradiationassisted stress corrosion cracking iascc of austenitic stainless steels that were irradiated in the halden reactor in simulation of irradiation induced degradation of boiling water reactor bwr core internal components. Irradiation induced stress corrosion cracking of austenitic stainless steels. Stress corrosion cracking scc is an important degradation mechanism for. Cracks were observed only in the irradiated area of sr am 316l ss as opposed to the unirradiated areas, fig. Irradiationassisted stress corrosion cracking iascc is a concern for both stainless steel and high nickel austenitic alloys irradiated in aqueous environments. Introduction the paper aims to give a present picture regarding what we know and do not yet know about irradiation assisted stress corrosion cracking iascc. The main environmental stressor that forms due to radiation is hydrogen embrittlement at crack tips. Irradiation assisted stress corrosion cracking iascc has been well documented both in the laboratory and in service over the past two decades.
The objective of this project is to determine whether deformation mode is a primary factor in the mechanism of irradiation assisted intergranular stress corrosion cracking of austenitic alloys in light watert reactor core components. The earliest incidents of irradiation assisted stress corrosion cracking iascc in bwrs occurred during the early 1960s and were associated with cracking of type 304 stainless steel fuel cladding, where the driving forces for cracking were the increasing tensile hoop stress in the cladding due to the swelling fuel and the highly oxidizing conditions in the water. Because cracking susceptibility is a function of radiation, stress and environment, the failure mechanism has been termed irradiation assisted stress corrosion cracking iascc. The iascc is a term used for stress corrosion cracking of structural materials appearing after irradiation in water environments. Gussev materials science and technology division oak ridge national laboratory date published. Irradiation assisted stress corrosion cracking iascc is a term which has been used in recent years to describe intergranular cracking showing little or no ductility which can occur in heavily irradiated struc tural components of nuclear reactor cores. Mechanism of irradiation assisted stress corrosion crack. Request pdf irradiation assisted stress corrosion cracking of stainless steels in a pwr environment a combined approach this work deals with the study of the irradiation assisted stress.
Irradiation assisted corrosion iac and irradiation assisted stress corrosion cracking iascc refer to the effect of irradiation on the enhancement of an inherent susceptibility to corrosion and stress corrosion cracking scc, respectively. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Irradiation has a profound effect on the stress corrosion cracking propensity of austenitic alloys in hightemperature water. Irradiation assisted stress corrosion cracking request pdf. Micromechanistic origin of irradiationassisted stress. The irradiationassisted stress corrosion cracking \iascc\ issue. An understanding of the mechanisms of iascc is required in order to. Irradiationassisted stress corrosion cracking iascc is a form of intergranular stress corrosion cracking igscc that has occurred infrequently during the last two decades in incore components. The effects of increased exposure to irradiation, stress, andor coolant can substantially increase susceptibility to stress corrosion cracking of austenitic steels in hightemperature water environments. Deformation mode will be controlled by both the stacking fault energy of the alloy and the degree of irradiation. The earliest incidents of irradiation assisted stress corrosion cracking iascc. A large experience base is available for conventional austenitic alloys from both commercial and experimental fission reactors. This article begins with an introduction to the iascc problem experienced in light water reactors, followed by a summary of existing plant and laboratory data.
Irradiation assisted stress corrosion cracking iascc was observed in the early 1960s. Irradiationassisted stress corrosion cracking osti. Numerous studies have shown that the degree of intergranular stress corrosion cracking increases with dose. Irradiationassisted stress corrosion cracking and impact. The purpose of these treatments was to restore the stress corrosion cracking scc resistance of the unirradiated material. Assessment of initial test conditions for experiments to. Uns s31600 stainless steel ss was much less susceptible to irradiation assisted stress corrosion cracking iascc than type 304 ss uns s30400 in nwc and hwc. In aging light water reactors see chapter 6, iascc has been observed to be a major mode of component failure of the austenitic steels. It was hypothesized that the slipoxidation mechanism for crack propagation was also. Stress assisted corrosion is also sometimes known as stress enhanced. Despite 30 years of experience, the underlying mechanisms of irradiation assisted stress corrosion cracking. Irradiation in high temperature water generally accelerates both general corrosion and stress corrosion cracking. Irradiationassisted stress corrosion cracking of austenitic. Grain boundary interaction sites and irradiation assisted stress corrosion crack initiation.
The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized austenitic. These mechanisms can act individually or act in combination to accelerate the aging processes. Irradiation assisted corrosion and stress corrosion. Increased swelling of certain components, such as baffle plates, means. While irradiation is believed to accelerate corrosion of most components in the core, the components initially observed to crack prematurely were primarily small components bolts, springs, etc. As a means of demonstrating inls capability for testing irradiation assisted stress corrosion cracking. Grain boundary composition and irradiationassisted stress. Quantitative prediction of environmentally assisted cracking. Irradiationassisted stress corrosion cracking both unirradiated and irradiated surface morphology of the tensile bars after cert testing is shown in fig.
Irradiationassisted stress corrosion cracking sciencedirect. Irradiation assisted stress corrosion cracking iascc is a phenomenon which has come under significant scrutiny in the last decade l41 because it continues to be a problem in light water reactor lwr core components. Shack nuclear engineering division argonne national laboratory, argonne, il 60439. Specifically, it is a stress attack directed at locations where applied or residual stresses are imparted to the metal. These findings have implications for modelling the mechanical properties of irradiated metals as well as in establishing the mechanism for disrupting the grain boundary oxide, which is a necessary prerequisite for irradiation assisted stress corrosion cracking. Introduction irradiation assisted stress corrosion cracking iascc is a term which has been used in recent years to describe intergranular cracking showing little or no ductility which can occur in heavily irradiated struc tural components of nuclear reactor cores. Sulfidation corrosion also known as sulfidic corrosion is a result of naturally occurring sulfur compounds found in crude oil. Potential lowtemperature behavior is assessed based on the temperature dependencies of intergranular ig scc in the absence of irradiation, radiation. Stress corrosion cracking and corrosion of candidate alloys for the supercritical water reactor concept. A novel explanation based on the variation of grain boundary composition is proposed to elucidate the localized nature of irradiationassisted stress corrosion cracking, i. Dislocation substructure vs transgranular stress corrosion susceptibility of single phase alloys. Stress assisted corrosion is a type of corrosion that can occur in metals due to elevated static tensile stress levels.
Effects of irradiation on intergranular stress corrosion cracking. Localized deformation as a primary cause of irradiation assisted stress corrosion cracking. This last phenomenon is referring to as irradiation assisted stress corrosion. On the mechanism of stress corrosion cracking in austenitic. Irradiation assisted stress corrosion cracking ias. Field experience as well as laboratory test results are considered to illustrate how iascc already impacts plant operation. Effects of irradiation on corrosion and environmentally. Download citation irradiation assisted stress corrosion cracking iascc irradiation assisted stress corrosion cracking iascc is a potential failure mode suffered by the corecomponents of.
The paper aims to give a present status of knowledge on irradiationassisted stress corrosion cracking iascc from the point of view of nuclear power plant life extension. Irradiation assisted stress corrosion cracking iascc occurs above a critical neutron fluence in lightwater reactor lwr water environments at 288 c, but very little information exists to indicate susceptibility as temperatures are reduced. Pdf irradiationassisted stress corrosion cracking and impact on. It is referred to as assisted because irradiation enhances, or accelerates the igscc process over the unirradiated state. Radiationinduced segregation and phase stability in candidate alloys for the advanced burner reactor. Owing largely to the water chemistry, differences between boiling water reactors bwrs and pressurized water reactors pwrs, iascc is a more serious issue in a bwrs. That research effort will define the materials to be used in future water reactors.
Dislocation substructure vs transgranular stress corrosion. The irradiationassisted stress corrosion cracking iascc. Irradiation assisted stress corrosion cracking iascc refers to intergranular stress corrosion cracking that is accelerated under the action of irradiation in light water reactor core components. Two kinds of material degradation phenomena, namely, irradiation assisted stress corrosion cracking iascc and intergranular stress corrosion cracking igscc for the irradiated, nonsensitized sss and the nonirradiated, thermally sensitized sss, respectively in water environment are known, although their behaviors are similar to each other. Introduction irradiationassisted stress corrosion cracking iascc involves the premature cracking and failure of materials in aggressive environments which is in duced or accelerated by ionizing radiation. Radiation damage and irradiationassisted stress corrosion. December 2010 prepared under the direction of the u. Localized deformation as a primary cause of irradiation. Irradiation assisted stress corrosion cracking iascc is a problem of growing importance in. Importance of molybdenum on irradiationassisted stress. Classical stress corrosion cracking scc and irradiation assisted stress corrosion cracking iascc continue to challenge the reliability of rpv internal components.
Effects of irradiation on intergranular stress corrosion cracking g. In an irradiation environment, scc is typically exacerbated by irradiationassisted stress corrosion cracking iascc. Effects of proton irradiation on the microstructure and. A mechanistic basis for irradiation assisted stress. The irradiation induced microstructure and irradiation assisted stress corrosion cracking iascc behavior of additively manufactured am 316l stainless steels produced by laser powder bed fusion were evaluated for the first time. Importance of molybdenum on irradiation assisted stress corrosion cracking in austenitic stainless steels. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.